Some Chemical Reactions of Sulphur Hexafluoride (2024)

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  • J. R. CASE1 &
  • F. NYMAN1

Nature volume193,page 473 (1962)Cite this article

Abstract

SULPHUR hexafluoride has customarily been considered to be chemically inert. It is unaffected by aqueous or fused alkali, ammonia or oxygen. The earliest report1 states that sulphur hexafluoride is reductively degraded by sulphur and selenium, vapours, and hydrogen sulphide at elevated temperatures, but these reactions have never been reinvestigated. The only substantiated chemical reaction of sulphur hexafluoride is that with a hot alkali metal, reaction with a film of sodium commencing at 200° 2. The great stability of sulphur hexafluoride is kinetic rather than thermodynamic in origin since it is thermodynamically unstable with respect to water3. The inability of nucleophilic reagents to attack the sulphur hexafluoride molecule can be ascribed to their failure to form an SN2 type transition state because the sulphur atom has no orbital of sufficiently low energy to permit its coordination with the unshared electron pair of the entering nucleophile. Attack by a nucleophilic reagent on a fluorine atom of sulphur hexafluoride is improbable for the same reason. However, there still remains the possibility of reaction with an electrophilic reagent, for example, a strong Lewis acid, the transition state of which is formed by co-ordination of the reagent with a fluorine atom using one of its lone electron pairs. This possibility does not appear to have been investigated until now.

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References

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  1. Imperial Chemical Industries, Ltd., Research Department, Alkali Division, Northwich, Cheshire

    J. R. CASE&F. NYMAN

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CASE, J., NYMAN, F. Some Chemical Reactions of Sulphur Hexafluoride. Nature 193, 473 (1962). https://doi.org/10.1038/193473a0

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Some Chemical Reactions of Sulphur Hexafluoride (2024)

FAQs

What is the reaction of sulphur hexafluoride? ›

The only substantiated chemical reaction of sulphur hexafluoride is that with a hot alkali metal, reaction with a film of sodium commencing at 200° 2. The great stability of sulphur hexafluoride is kinetic rather than thermodynamic in origin since it is thermodynamically unstable with respect to water3.

What are the reactions of SF6? ›

Sulphur hexafluoride reacts readily with electrically exploded Al, Zr, Ag and Pt to form SF4 and metal fluorides. Ordinarily SF6 is relatively inert toward these metals at fairly high temperatures.

What are the chemical properties of sulfur hexafluoride? ›

Sulfur hexafluoride is a nonpolar, organic, colorless, odorless, noninflammable, nontoxic, and long-lived (atmospheric lifetime of 800–3200 years) gas. Its structure consists of six fluorine atoms bonded with one sulfur atom at the center.

Which formula responses represent sulfur hexafluoride? ›

A molecule of sulfur hexafluoride contains one sulfur atom and six fluorine atoms. The chemical formula for sulfur hexafluoride is SF6.

What is the chemical reaction of sulfur oxygen? ›

sulfur + oxygen →

Sulfur burns in oxygen to form sulfur dioxide. Your teacher will not demonstrate this reaction, because the sulfur dioxide that forms is a poisonous gas that you and your classmates should not be exposed to.

What is the chemical reaction of burning of sulphur? ›

The sulphur furnace is used for the complete combustion of molten sulphur (S8) with oxygen to SO2 according to the reaction S + O2 → SO2 (△Hf @25°C = −70.94 kcal/mol). The reaction is highly exothermic, resulting in a large temperature rise.

What are 5 chemical properties of sulfur? ›

Chemical properties of sulphur - Health effects of sulphur - Environmental effects of sulphur
Atomic number16
Electronegativity according to Pauling2.5
Density2.07 g.cm -3 at 20 °C
Melting point113 °C
Boiling point445 °C
10 more rows

What are the facts about sulfur hexafluoride? ›

Protect the Environment - SF6 is the most potent greenhouse gas known. It is 23,500 times more effective at trapping infrared radiation than an equivalent amount of CO2 and stays in the atmosphere for 3,200 years.

What is the chemical bond of sulfur hexafluoride? ›

Therefore, the type of chemical bond found in Sulphur hexafluoride is a Covalent bond.

Does sulfur hexafluoride dissolve in water? ›

SF6 has an octahedral geometry, consisting of six fluorine atoms attached to a central sulfur atom. It is a hypervalent molecule. Typical for a nonpolar gas, SF6 is poorly soluble in water but quite soluble in nonpolar organic solvents.

What is another name for sulfur hexafluoride? ›

Sulfur hexafluoride
Names
Systematic IUPAC name Hexafluoro-λ6-sulfane
Other names Elagas Esaflon Sulfur(VI) fluoride Sulfuric fluoride
Identifiers
CAS Number2551-62-4
62 more rows

How to make sulfur hexafluoride? ›

It is usually made by burning sulphur in an atmosphere of fluorine, though it can be prepared by pyrolysis of SF5Cl (whose synthesis does not require the use of elemental fluorine).

What does sulfur hexafluoride do to your body? ›

* Sulfur Hexafluoride can irritate the skin causing a rash or burning feeling on contact. Direct skin contact can cause frostbite. * Sulfur Hexafluoride may cause severe eye burns leading to permanent damage. * Breathing Sulfur Hexafluoride can irritate the nose and throat.

How does sulfur hexafluoride change your voice? ›

Sulfur hexafluoride makes your voice sound very low because sound travels slower in heavy gases.

How toxic is sulfur hexafluoride? ›

SF6 is a non-toxic, odorless gas with few, if any, potential health effects. It is extremely unlikely that the general public or workers would be exposed to concentrations of sulfur hexafluoride resulting in any health effects.

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